Polyethylene and EVA
Polyethylene (abbreviated PE) or polyethene (IUPAC name polyethene or poly(methylene)) is the most common plastic. The annual global production is around 80 million tonnes. Its primary use is in packaging (plastic bags, plastic films, geomembranes, containers including bottles, etc.). Many kinds of polyethylene are known, with most having the chemical formula (C2H4)n. PE is usually a mixture of similar polymers of ethylene with various values of n.
Ethylene-vinyl acetate (EVA), also known as poly (ethylene-vinyl acetate) (PEVA), is the copolymer of ethylene and vinyl acetate. The weight percent vinyl acetate usually varies from 10 to 40%, with the remainder being ethylene.
Broadly speaking, there are three different types of EVA copolymer, which differ in the vinyl acetate (VA) content and the way the materials are used.
The EVA copolymer which is based on a low proportion of VA (approximately up to 4%) may be referred to as vinyl acetate modified polyethylene. It is a copolymer and is processed as a thermoplastics material – just like low density polyethylene. It has some of the properties of a low density polyethylene but increased gloss (useful for film), softness and flexibility. Generally considered as a non-toxic material.
The EVA copolymer which is based on a medium proportion of VA (approximately 4 to 30%) is referred to as thermoplastic ethylene-vinyl acetate copolymer and is a thermoplastic elastomer material. It is not vulcanized but has some of the properties of a rubber or of plasticized polyvinyl chloride particularly at the higher end of the range. May be filled and both filled and unfilled materials have good low temperature properties and are tough. The materials with approximately 11% VA are used as hot melt adhesives.
The EVA copolymer which is based on a high proportion of VA (greater than 40%) is referred to as ethylene-vinyl acetate rubber.
EVA is an elastomeric polymer that produces materials which are "rubber-like" in softness and flexibility. The material has good clarity and gloss, low-temperature toughness, stress-crack resistance, hot-melt adhesive waterproof properties, and resistance to UV radiation. EVA has a distinctive vinegar-like odor and is competitive with rubber and vinyl products in many electrical applications.